Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

Kazushi Arata

doi:10.1039/B822795K

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Green Chemistry

Issue 11, 2009

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Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

Kazushi Arata

Green Chem., 2009, 11, 1719-1728

DOI: 10.1039/B822795K
Received 18 Dec 2008, Accepted 12 Aug 2009
First published on the web 17 Sep 2009

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Recent studies on organic syntheses catalyzed by solid superacids, which are sulfate-supported metal oxides and tungsten- or molybdenum-supported metal oxides, are reviewed. The synthetic reactions are Friedel–Crafts acylations, reactions between amines and ketones, esterifications of acids with alcohols, and others. The catalysts are satisfactorily active in a heterogeneous liquid–solid system, recoverable, and reusable, and they offer new opportunities for developing environmentally benign and friendly processes in organic syntheses.

Abstract from Methods in Organic Synthesis 2010

A review, with 112 references, summarizing recent studies on organic syntheses catalyzed by sulfate-supported metal oxides and tungsten- or molybdenum-supported metal oxides, mainly sulfated zirconia and related compounds, which offer new opportunities for developing environmentally benign and friendly processes in organic syntheses.

Abstract from Catalysts & Catalysed Reactions 2010

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Green Chemistry

Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

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