Green chemistry aspects of fluorous techniques—opportunities and challenges for small-scale organic synthesis

Wei Zhang

doi:10.1039/B820740B

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Green Chemistry

Issue 7, 2009

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Green chemistry aspects of fluorous techniques—opportunities and challenges for small-scale organic synthesis

Wei Zhang

Green Chem., 2009, 11, 911-920

DOI: 10.1039/B820740B
Received 20 Nov 2008, Accepted 27 Apr 2009
First published on the web 14 May 2009

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Described in this paper is a personal overview of the green chemistry aspects of fluorous technologies. The unique phase separation and broad combinatorial capabilities of fluorous technologies have led to the development of fluorous chromatography-free separations, chemical recycling techniques, atom economic reactions, energy-focused microwave reactions, metal-free organocatalysis, aqueous media reactions, and modified reagents. These green chemistry techniques have been demonstrated in discovery chemistry, medicinal chemistry, and academic research labs dealing with small-scale organic synthesis. Issues such as the environmental impact of fluorous chemicals are also discussed.

Abstract from Chemical Hazards in Industry 2009

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Green Chemistry

Green chemistry aspects of fluorous techniques—opportunities and challenges for small-scale organic synthesis

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