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Issue 7, 2009
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Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

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Abstract

The use of ionic liquids for the immobilization of rhodium siloxide complexes has permitted development of highly effective catalysts for the hydrosilylation processes. Herein, we report the synthesis of organosilicon compounds in a biphasic reaction setup, allowing separation of the product, recovery and reuse of the catalyst, which is fundamental from the point of view of “green chemistry”.

Graphical abstract: Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

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Publication details

The article was received on 03 Nov 2008, accepted on 09 Apr 2009 and first published on 29 Apr 2009


Article type: Paper
DOI: 10.1039/B819310J
Citation: Green Chem., 2009,11, 1045-1051
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    Hydrosilylation of functionalised olefins catalysed by rhodium siloxide complexes in ionic liquids

    H. Maciejewski, K. Szubert, B. Marciniec and J. Pernak, Green Chem., 2009, 11, 1045
    DOI: 10.1039/B819310J

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