Catalytic reactions using superacids in new types of ionic liquids

Mark A. Harmer; Christopher P. Junk; Vsevolod V. Rostovtsev; William J. Marshall; Liane M. Grieco; Jemma Vickery; Robert Miller; Stella Work

doi:10.1039/B818788F

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Green Chemistry

Issue 4, 2009

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Catalytic reactions using superacids in new types of ionic liquids

Mark A. Harmer , Christopher P. Junk , Vsevolod V. Rostovtsev , William J. Marshall , Liane M. Grieco , Jemma Vickery , Robert Miller and Stella Work

Green Chem., 2009, 11, 517-525

DOI: 10.1039/B818788F
Received 23 Oct 2008, Accepted 13 Jan 2009
First published on the web 09 Feb 2009

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We will describe the use of superacids, in particular 1,1,2,2-tetrafluoroethanesulfonic acid (TFESA) and 1,1,2,3,3,3-hexafluoropropanesulfonic acid (HFPSA) in the presence of ionic liquids for improved chemical processing for a range of industrially important chemical reactions. In a number of cases the reaction mixture starts as a single phase, allowing for high reactivity, then separates into two phases upon completion of the reaction. This allows for ease of product separation P. T. Anastas and T. C. Williamson, Green Chemistry: Frontiers in Benign Chemical Syntheses and Processes, Oxford University Press, 1998.¹

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Articles By

Mark A. Harmer
Christopher P. Junk
Vsevolod V. Rostovtsev
William J. Marshall
Liane M. Grieco
Jemma Vickery
Robert Miller
Stella Work

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Green Chemistry

Catalytic reactions using superacids in new types of ionic liquids

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