Issue 46, 2009
From the journal:

Dalton Transactions

First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands†

Antoine Buchard,a   Audrey Auffrant,a   Louis Ricard,a   Xavier F. Le Goff,a   Rachel H. Platel,b   Charlotte K. Williamsb  and  Pascal Le Floch*a  

* Corresponding authors

a Ecole Polytechnique, Laboratoire Hétéroéléments et Coordination, CNRS, Palaiseau Cedex, France
E-mail: pascal.lefloch@polytechnique.edu
Fax: (+) 33 (0)1 69 33 44 40

b Department of Chemistry, Imperial College London, London, United Kingdom

Abstract

Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd–C single and multiple bonds.

Graphical abstract: First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

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Article information

DOI
https://doi.org/10.1039/B918971H
Article type
Paper
Submitted
24 Jun 2009
Accepted
25 Sep 2009
First published
26 Oct 2009

Dalton Trans., 2009, 10219-10222

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First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

A. Buchard, A. Auffrant, L. Ricard, X. F. Le Goff, R. H. Platel, C. K. Williams and P. Le Floch, Dalton Trans., 2009, 10219 DOI: 10.1039/B918971H

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