First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard; Audrey Auffrant; Louis Ricard; Xavier F. Le Goff; Rachel H. Platel; Charlotte K. Williams; Pascal Le Floch

doi:10.1039/B918971H

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Dalton Transactions

Issue 46, 2009

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First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard , Audrey Auffrant , Louis Ricard , Xavier F. Le Goff , Rachel H. Platel , Charlotte K. Williams and Pascal Le Floch

Dalton Trans., 2009, 10219-10222

DOI: 10.1039/B918971H
Received 24 Jun 2009, Accepted 25 Sep 2009
First published on the web 26 Oct 2009

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Abstract
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Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd–C single and multiple bonds.

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Antoine Buchard
Audrey Auffrant
Louis Ricard
Xavier F. Le Goff
Rachel H. Platel
Charlotte K. Williams
Pascal Le Floch

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Dalton Transactions

First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

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