A new bifunctional GdIII complex of enhanced efficacy for MR-molecular imaging applications

Lorenzo Tei; Giuseppe Gugliotta; Zsolt Baranyai; Mauro Botta

doi:10.1039/B917566K

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Dalton Transactions

Issue 44, 2009

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A new bifunctional Gd^III complex of enhanced efficacy for MR-molecular imaging applications

Lorenzo Tei , Giuseppe Gugliotta , Zsolt Baranyai and Mauro Botta

Dalton Trans., 2009, 9712-9714

DOI: 10.1039/B917566K
Received 19 Jun 2009, Accepted 04 Sep 2009
First published on the web 15 Sep 2009

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Increasing the length of the carboxyamide arm of a GdDOTA monoamide (DOTA = 1,4,7,10-tetraaza-1,4,7,10-tetrakis(carboxymethyl)cyclododecane) complex from acetic to propionic accelerates the water exchange rate (k_ex) by nearly two orders of magnitude; the ¹H relaxivity of the corresponding macromolecular derivatives may then be remarkably enhanced in MRI-based molecular imaging applications, as exemplified in the case of micellar systems.

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Dalton Transactions

A new bifunctional Gd^III complex of enhanced efficacy for MR-molecular imaging applications

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