β-Diketiminate C–H activation with heavier group 2 alkyls

Mark R. Crimmin; Anthony G. M. Barrett; Michael S. Hill; Dugald J. MacDougall; Mary F. Mahon; Panayiotis A. Procopiou

doi:10.1039/B917466B

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Dalton Transactions

Issue 44, 2009

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β-Diketiminate C–H activation with heavier group 2 alkyls

Mark R. Crimmin , Anthony G. M. Barrett , Michael S. Hill , Dugald J. MacDougall , Mary F. Mahon and Panayiotis A. Procopiou

Dalton Trans., 2009, 9715-9717

DOI: 10.1039/B917466B
Received 24 Aug 2009, Accepted 11 Sep 2009
First published on the web 21 Sep 2009

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Abstract
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Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe₃)₂}₂(THF)_n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual ‘C–H activation’ products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

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Articles By

Mark R. Crimmin
Anthony G. M. Barrett
Michael S. Hill
Dugald J. MacDougall
Mary F. Mahon
Panayiotis A. Procopiou

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Dalton Transactions

β-Diketiminate C–H activation with heavier group 2 alkyls

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