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Issue 44, 2009
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β-Diketiminate C–H activation with heavier group 2 alkyls

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Abstract

Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe3)2}2(THF)n] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic β-diketiminato alkyl when M = Ca or unusual ‘C–H activation’ products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

Graphical abstract: β-Diketiminate C–H activation with heavier group 2 alkyls

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Publication details

The article was received on 24 Aug 2009, accepted on 11 Sep 2009 and first published on 21 Sep 2009


Article type: Communication
DOI: 10.1039/B917466B
Citation: Dalton Trans., 2009, 9715-9717
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    β-Diketiminate C–H activation with heavier group 2 alkyls

    M. R. Crimmin, A. G. M. Barrett, M. S. Hill, D. J. MacDougall, M. F. Mahon and P. A. Procopiou, Dalton Trans., 2009, 9715
    DOI: 10.1039/B917466B

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