Remarkable thermal stability of Eu(4-phosphonobenzoate): structure investigations and luminescence properties

Jean-Michel Rueff; Nicolas Barrier; Sophie Boudin; Vincent Dorcet; Vincent Caignaert; Philippe Boullay; Gary B. Hix; Paul-Alain Jaffrès

doi:10.1039/B913590C

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Dalton Transactions

Issue 47, 2009

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Remarkable thermal stability of Eu(4-phosphonobenzoate): structure investigations and luminescence properties

Jean-Michel Rueff , Nicolas Barrier , Sophie Boudin , Vincent Dorcet , Vincent Caignaert , Philippe Boullay , Gary B. Hix and Paul-Alain Jaffrès

Dalton Trans., 2009, 10614-10620

DOI: 10.1039/B913590C
Received 07 Jul 2009, Accepted 29 Sep 2009
First published on the web 02 Nov 2009

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Abstract
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A new 3D rare-earth hybrid material Eu(p-O₃PC₆H₄COO) has been synthesised by a hydrothermal route from Eu(NO₃)₃·5H₂O and the rigid precursor, 4-phosphonobenzoic acid. The structure of Eu(p-O₃PC₆H₄COO) has been solved by X-ray diffraction on a powder sample and is described as an inorganic network in which both carboxylic and phosphonic acid groups are linked to Eu ions forming a three-dimensional architecture. Thermal analysis performed on this compound has underlined its remarkable stability up to 510 °C and an optical study has been conducted to examine its luminescence properties that have been related to the structure of the material. The structural and luminescence properties have also been compared with the related material Eu phenylphosphonate.

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Supplementary Info

CIF file for powder X-ray structure for Eu(p-O₃PC₆H₄COO)
TXT (11K)

Articles By

Jean-Michel Rueff
Nicolas Barrier
Sophie Boudin
Vincent Dorcet
Vincent Caignaert
Philippe Boullay
Gary B. Hix
Paul-Alain Jaffrès

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Dalton Transactions

Remarkable thermal stability of Eu(4-phosphonobenzoate): structure investigations and luminescence properties

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