Platinum(II) mediated Csp3-H activation of tetramethylthiourea

Serena Fantasia; Alessandro Pasini; Steven P. Nolan

doi:10.1039/B911164F

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Dalton Transactions

Issue 38, 2009

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Platinum(II) mediated C^sp3-H activation of tetramethylthiourea

Serena Fantasia , Alessandro Pasini and Steven P. Nolan

Dalton Trans., 2009, 8107-8110

DOI: 10.1039/B911164F
Received 08 Jun 2009, Accepted 21 Jul 2009
First published on the web 10 Aug 2009

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Abstract
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The C–H activation of the methyl group of tetramethylthiourea by cis-[PtL₂(NO₃)₂] (L = phosphine or N-heterocyclic carbene) has been investigated as a function of the ligand L. The presence of an electron-withdrawing group on the tertiary phosphine was found to promote the process. Moreover, when an excess of nitrate anion is present in the reaction mixture, the rate of C–H bond activation is retarded, suggesting the key role of an unsaturated tri-coordinate Pt^II species as intermediate.

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Dalton Transactions

Platinum(II) mediated C^sp3-H activation of tetramethylthiourea

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