Half-titanocenes containing anionic ancillary donor ligands as promising new catalysts for precise olefin polymerisation

Kotohiro Nomura

doi:10.1039/B910407K

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Dalton Transactions

Issue 41, 2009

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Half-titanocenes containing anionic ancillary donor ligands as promising new catalysts for precise olefin polymerisation

Kotohiro Nomura

Dalton Trans., 2009, 8811-8823

DOI: 10.1039/B910407K
Received 27 May 2009, Accepted 08 Jul 2009
First published on the web 06 Aug 2009
This article is part of the collection: Metal-Catalysed Polymerisation

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Recent efforts concerning nonbridged half-titanocenes containing anionic donor ligand of the type, Cp′TiX₂(Y) [Cp′ = cyclopentadienyl group; X = halogen, alkyl; Y = anionic ancillary donor ligands such as aryloxo, ketimide etc.], as new types of olefin polymerisation catalysts have been reviewed. It has been demonstrated that these complexes displayed unique characteristics especially for ethylene copolymerisation affording new polymers by efficient incorporation of bulky olefins (so called “traditionally unreactive” monomers in transition metal catalysed coordination polymerisation), that have not been attained by the ordinary catalysts.

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Dalton Transactions

Half-titanocenes containing anionic ancillary donor ligands as promising new catalysts for precise olefin polymerisation

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