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Issue 33, 2009
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A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

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Abstract

Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)2Co2Na2(H2O)2]18−, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.

Graphical abstract: A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

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Publication details

The article was received on 15 Apr 2009, accepted on 10 Jun 2009 and first published on 09 Jul 2009


Article type: Communication
DOI: 10.1039/B907410D
Citation: Dalton Trans., 2009, 6483-6486
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    A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

    C. Ritchie, F. Li, C. P. Pradeep, D. Long, L. Xu and L. Cronin, Dalton Trans., 2009, 6483
    DOI: 10.1039/B907410D

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