Issue 33, 2009
From the journal:

Dalton Transactions

A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−†

Chris Ritchie,‡a   Fengyan Li,‡ab   Chullikkattil P. Pradeep,a   De-Liang Long,a   Lin Xu*b  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Fax: +44 141 330 4888
Tel: +44 141 330 6650

b Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, People's Republic of China
E-mail: linxu@nenu.edu.cn
Fax: +86 431 85099668
Tel: +86 431 85099668

Abstract

Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)2Co2Na2(H2O)2]18−, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.

Graphical abstract: A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

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Article information

DOI
https://doi.org/10.1039/B907410D
Article type
Communication
Submitted
15 Apr 2009
Accepted
10 Jun 2009
First published
09 Jul 2009

Dalton Trans., 2009, 6483-6486

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A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

C. Ritchie, F. Li, C. P. Pradeep, D. Long, L. Xu and L. Cronin, Dalton Trans., 2009, 6483 DOI: 10.1039/B907410D

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