Fused polycyclic nucleophilic carbenes – synthesis, structure, and function

Anthony J. Arduengo, III; Luigi I. Iconaru

doi:10.1039/B907211J

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Dalton Transactions

Issue 35, 2009

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Fused polycyclic nucleophilic carbenes – synthesis, structure, and function

Anthony J. Arduengo, III and Luigi I. Iconaru

Dalton Trans., 2009, 6903-6914

DOI: 10.1039/B907211J
Received 08 Apr 2009, Accepted 10 Jun 2009
First published on the web 21 Jul 2009
This article is part of the collection: N-heterocyclic carbenes

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Abstract
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Interest in stable nucleophilic carbenes has grown rapidly since the isolation of the first “bottle-able” example in 1991. Not only has the structural variation of this class of compounds seen an incredible expansion from laboratories around the world, but the chemical reactivity of these compounds has opened many new opportunities for improvements in chemical transformations and invention of new processes. This article reflects our particular interest in fused polycyclic carbenes and focuses on this broad chemical class from both a structural and reactivity perspective.

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Dalton Transactions

Fused polycyclic nucleophilic carbenes – synthesis, structure, and function

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