Mechanisms of C–H bond activation: rich synergy between computation and experiment

Youcef Boutadla; David L. Davies; Stuart A. Macgregor; Amalia I. Poblador-Bahamonde

doi:10.1039/B904967C

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Dalton Transactions

Issue 30, 2009

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Mechanisms of C–H bond activation: rich synergy between computation and experiment

Youcef Boutadla , David L. Davies , Stuart A. Macgregor and Amalia I. Poblador-Bahamonde

Dalton Trans., 2009, 5820-5831

DOI: 10.1039/B904967C
Received 11 Mar 2009, Accepted 19 May 2009
First published on the web 10 Jun 2009
This article is part of the collection: The synergy between theory and experiment

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Abstract
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Recent computational studies of C–H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C–H bonds. The term ‘ambiphilic metal ligand activation’ (AMLA) is introduced to describe such reactions.

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Mechanisms of C–H bond activation: rich synergy between computation and experiment

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