A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Zhuojia Lin; David S. Wragg; Philip Lightfoot; Russell E. Morris

doi:10.1039/B904450G

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Dalton Transactions

Issue 27, 2009

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A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Zhuojia Lin , David S. Wragg , Philip Lightfoot and Russell E. Morris

Dalton Trans., 2009, 5287-5289

DOI: 10.1039/B904450G
Received 02 Apr 2009, Accepted 13 May 2009
First published on the web 21 May 2009

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Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate–borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.

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Dalton Transactions

A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

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