Hydrometalation of fluoroallenes

Moritz F. Kühnel; Dieter Lentz

doi:10.1039/B903300A

skip RSC | ChemSpider | Feedback

Home > Journals > Dalton Transactions > Hydrometalation of fluo...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dalton Transactions

Issue 24, 2009

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Paper

Previous Article | Next Article

Hydrometalation of fluoroallenes

Moritz F. Kühnel and Dieter Lentz

Dalton Trans., 2009, 4747-4755

DOI: 10.1039/B903300A
Received 17 Feb 2009, Accepted 02 Apr 2009
First published on the web 06 May 2009

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

Tetrafluoroallene (1) and 1,1-difluoroallene (2) react under mild conditions with group 6 and 7 transition metal hydride complexes Cp(CO)₃MoH (4), CO₅MnH (5), Cp₂WH₂ (9), and Cp₂MoH₂ (10) to give the new fluoropropenyl complexes 6a, 7a, 11, 12, 15a–c, and 16a–c, which were characterized by single crystal X-ray diffraction. Complexes 6a and 7a undergo thermally induced 1,3-fluorine migration, whereas 11 and 12 show hindered rotation around the carbon metal single bond.

This may take some time to load.

Supplementary Info

Crystal structure data
TXT (85K)

Terms & Conditions|Privacy |Accessibility|ACAP Enabled

Dalton Transactions

Hydrometalation of fluoroallenes

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Articles By