Nitrene transfer reactions mediated by metallo-porphyrin complexes

Simone Fantauzzi; Alessandro Caselli; Emma Gallo

doi:10.1039/B902929J

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Dalton Transactions

Issue 28, 2009

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Nitrene transfer reactions mediated by metallo-porphyrin complexes

Simone Fantauzzi , Alessandro Caselli and Emma Gallo

Dalton Trans., 2009, 5434-5443

DOI: 10.1039/B902929J
Received 11 Feb 2009, Accepted 04 Mar 2009
First published on the web 25 Mar 2009

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Nitrene transfer reactions represent a useful methodology to synthesize in a few steps high added-value compounds used as organic intermediates. Herein, we describe the catalytic activity of metal porphyrin complexes in a wide range of reactions such as C–H hydrocarbon amination and olefin aziridination to synthesize nitrogen containing molecules. All the most important nitrene sources have been reviewed stressing the potentiality and limits of each one in the particular class of chemical transformation.

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Dalton Transactions

Nitrene transfer reactions mediated by metallo-porphyrin complexes

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