Away from phosgene: reductive carbonylation of nitroarenes and oxidative carbonylation of amines, understanding the mechanism to improve performance

Fabio Ragaini

doi:10.1039/B902425P

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Dalton Transactions

Issue 32, 2009

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Away from phosgene: reductive carbonylation of nitroarenes and oxidative carbonylation of amines, understanding the mechanism to improve performance

Fabio Ragaini

Dalton Trans., 2009, 6251-6266

DOI: 10.1039/B902425P
Received 04 Feb 2009, Accepted 30 Mar 2009
First published on the web 07 May 2009

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Recent progress, with some emphasis on the author's own work, on the understanding of the mechanism of the reductive carbonylation of nitroarenes and of the oxidative carbonylation of amines is discussed, highlighting the close connection between the two reactions and trying to unify scattered data in the literature. Isocyanates, carbamates and ureas can be obtained by either procedure, without the need for the use of the toxic and corrosive phosgene.

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Dalton Transactions

Away from phosgene: reductive carbonylation of nitroarenes and oxidative carbonylation of amines, understanding the mechanism to improve performance

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