A redox-fluorescent molecular switch based on a heterobimetallic Ir(III) complex with a ferrocenyl azaheterocycle as ancillary ligand

Fabiola Zapata; Antonio Caballero; Arturo Espinosa; Alberto Tárraga; Pedro Molina

doi:10.1039/B902055C

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Dalton Transactions

Issue 20, 2009

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A redox-fluorescent molecular switch based on a heterobimetallic Ir(III) complex with a ferrocenyl azaheterocycle as ancillary ligand

Fabiola Zapata , Antonio Caballero , Arturo Espinosa , Alberto Tárraga and Pedro Molina

Dalton Trans., 2009, 3900-3902

DOI: 10.1039/B902055C
Received 30 Jan 2009, Accepted 10 Feb 2009
First published on the web 20 Feb 2009
This article is part of the collection: Supramolecular photochemistry

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Abstract
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The synthesis, electronic and spectroelectrochemical studies of a cyclometalated heteroleptic Ir(III) complex containing a redox active ferrocenyl imidazophenanthroline ancillary ligand, is presented. Depending on the oxidation state of the ferrocene, controlled by external electrochemical stimuli, the emission fluorescence intensity of this bistable heterometallic complex can be modulated.

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Fabiola Zapata
Antonio Caballero
Arturo Espinosa
Alberto Tárraga
Pedro Molina

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Dalton Transactions

A redox-fluorescent molecular switch based on a heterobimetallic Ir(III) complex with a ferrocenyl azaheterocycle as ancillary ligand

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