Sensitised luminescence in lanthanide containing arrays and d–f hybrids

Stephen Faulkner; Louise S. Natrajan; William S. Perry; Daniel Sykes

doi:10.1039/B902006C

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Dalton Transactions

Issue 20, 2009

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Sensitised luminescence in lanthanide containing arrays and d–f hybrids

Stephen Faulkner , Louise S. Natrajan , William S. Perry and Daniel Sykes

Dalton Trans., 2009, 3890-3899

DOI: 10.1039/B902006C
Received 30 Jan 2009, Accepted 04 Mar 2009
First published on the web 06 Apr 2009
This article is part of the collection: Supramolecular photochemistry

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Abstract
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Sensitised luminescence from lanthanide complexes offers many potential advantages in imaging and assay, particularly when coupled with time-gating protocols that can be used to gate out background signal. In this perspective, we discuss the routes by which lanthanide arrays and polymetallic d–f hybrids can be prepared by conventional synthesis and self-assembly, and discuss and evaluate the possibilities for exploiting and evaluating the intermediates in the sensitisation process, with particular emphasis on the mechanisms of energy transfer.

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Dalton Transactions

Sensitised luminescence in lanthanide containing arrays and d–f hybrids

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