Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

Sanjit Nayak; Lianne M. C. Beltran; Yanhua Lan; Rodolphe Clérac; Nigel G. R. Hearns; Wolfgang Wernsdorfer; Christopher E. Anson; Annie K. Powell

doi:10.1039/B820818M

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Two edge-sharing Mn^II₄Mn^III₆ supertetrahedra give an anisotropic S = 28 ± 1 Mn^II₆Mn^III₁₁ complex†

Sanjit Nayak,^a Lianne M. C. Beltran,^a Yanhua Lan,^a Rodolphe Clérac,^bc Nigel G. R. Hearns,^bc Wolfgang Wernsdorfer,^d Christopher E. Anson^a and Annie K. Powell*^a

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* Corresponding authors

^a Institut für Anorganische Chemie der Universität Karlsruhe, 76131 Karlsruhe, Germany
E-mail: powell@aoc.uni-karlsruhe.de
Fax: +49 721 6088142
Tel: +49721 6082135

^b CNRS, UPR 8641, Centre de Recherche Paul Pascal (CRPP), 115 avenue du Dr. Albert Schweitzer, Pessac, France

^c Université de Bordeaux, UPR 8641, Pessac, France

^d Laboratoire Louis Néel-CNRS, avenue des Martyrs, Grenoble, France

Abstract

A complex with a [Mn^II₆Mn^III₁₁] core results via formal fusion of two isotropic Mn^II₄Mn^III₆ supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.

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Article information

DOI: https://doi.org/10.1039/B820818M
Article type: Communication
Submitted: 20 Nov 2008
Accepted: 20 Jan 2009
First published: 10 Feb 2009

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Dalton Trans., 2009, 1901-1903

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Two edge-sharing Mn^II₄Mn^III₆ supertetrahedra give an anisotropic S = 28 ± 1 Mn^II₆Mn^III₁₁ complex

S. Nayak, L. M. C. Beltran, Y. Lan, R. Clérac, N. G. R. Hearns, W. Wernsdorfer, C. E. Anson and A. K. Powell, Dalton Trans., 2009, 1901 DOI: 10.1039/B820818M

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Dalton Transactions