Issue 11, 2009

Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

Abstract

A complex with a [MnII6MnIII11] core results via formal fusion of two isotropic MnII4MnIII6 supertetrahedra along a common edge leading to a high spin ground state anisotropic system showing Mvs. H hysteresis loops below 1 K.

Graphical abstract: Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

Supplementary files

Article information

Article type
Communication
Submitted
20 Nov 2008
Accepted
20 Jan 2009
First published
10 Feb 2009

Dalton Trans., 2009, 1901-1903

Two edge-sharing MnII4MnIII6 supertetrahedra give an anisotropic S = 28 ± 1 MnII6MnIII11 complex

S. Nayak, L. M. C. Beltran, Y. Lan, R. Clérac, N. G. R. Hearns, W. Wernsdorfer, C. E. Anson and A. K. Powell, Dalton Trans., 2009, 1901 DOI: 10.1039/B820818M

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