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Issue 14, 2009
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SQUID magnetometry as a tool for following a clock reaction in solution

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Abstract

SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(II)EDTA]2 by H2O2, in real time and it was shown that, in combination with other methods (e.g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.

Graphical abstract: SQUID magnetometry as a tool for following a clock reaction in solution

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Publication details

The article was received on 07 Nov 2008, accepted on 28 Jan 2009 and first published on 18 Feb 2009


Article type: Communication
DOI: 10.1039/B819977A
Citation: Dalton Trans., 2009,0, 2467-2469
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    SQUID magnetometry as a tool for following a clock reaction in solution

    R. Evans, K. B. Henbest, M. A. Hayward, M. M. Britton, K. Maeda and C. R. Timmel, Dalton Trans., 2009, 0, 2467
    DOI: 10.1039/B819977A

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