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Issue 37, 2009
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Reaction of isocyanides with a molybdenum complex containing a tridentate silyl-phosphine ligand: the Si ligand effect on site preference of the isocyanide ligands

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Abstract

A molybdenum trihydride complex containing a tridentate silyl-phosphine ligand reacts with isocyanides to give isocyanide complexes, in which the Si atom and the isocyanides are cis to each other; the preferred configuration in the resulting complexes is reasonably explicable provided the Si fragment is acting as a good π-acid ligand.

Graphical abstract: Reaction of isocyanides with a molybdenum complex containing a tridentate silyl-phosphine ligand: the Si ligand effect on site preference of the isocyanide ligands

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Publication details

The article was received on 10 Nov 2008, accepted on 29 Jun 2009 and first published on 28 Jul 2009


Article type: Paper
DOI: 10.1039/B819837C
Citation: Dalton Trans., 2009,0, 7684-7687
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    Reaction of isocyanides with a molybdenum complex containing a tridentate silyl-phosphine ligand: the Si ligand effect on site preference of the isocyanide ligands

    M. Minato, G. Kikutsuji, M. Kakeya, K. Osakada and M. Yamasaki, Dalton Trans., 2009, 0, 7684
    DOI: 10.1039/B819837C

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