Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

María A. Garralda

doi:10.1039/B817263C

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Dalton Transactions

Issue 19, 2009

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Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

María A. Garralda

Dalton Trans., 2009, 3635-3645

DOI: 10.1039/B817263C
Received 02 Oct 2008, Accepted 08 Jan 2009
First published on the web 12 Feb 2009

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This perspective focuses on the aldehyde C–H activation promoted by late transition metals, including the chelation-assisted reactions. The mechanisms currently accepted for different metal complexes, the reactivity of acyl hydrido species formed, and the reactions promoted on further aldehyde when using excess reagent are discussed. Homogeneous catalytic aldehyde decarbonylation or dimerization reactions are also reviewed.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 75 references, of aldehyde C–H bond acivation promoted by late transition metal complexes, including coverage of homogeneous catalytic aldehyde decarbonylation and dimerisation reactions.

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Dalton Transactions

Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

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