Aluminium, zinc, gallium, and cadmium complexes supported by a monoanionic [N2P2] ligand

Stefan G. Minasian; John Arnold

doi:10.1039/B815854A

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Dalton Transactions

Issue 1, 2009

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Aluminium, zinc, gallium, and cadmium complexes supported by a monoanionic [N₂P₂] ligand

Stefan G. Minasian and John Arnold

Dalton Trans., 2009, 106-110

DOI: 10.1039/B815854A
Received 10 Sep 2008, Accepted 30 Sep 2008
First published on the web 06 Nov 2008

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Metal–halide complexes of main-group metals Al, Ga, Zn, and Cd supported by the new sterically and electronically versatile monoanionic ligand, ^tBuN(H)SiMe₂N(CH₂CH₂PⁱPr₂)₂, H[N₂P₂], are described. The metal–alkyl complex [N₂P₂]AlMe₂ (4) was prepared by two metathesis reactions of [N₂P₂]AlCl₂ (1) and 2MeLi, as well as [N₂P₂]Li and Me₂AlCl. All compounds were characterized by standard analytical techniques; in addition, [N₂P₂]AlCl₂ (1), [N₂P₂]GaCl₂ (3), and [N₂P₂]CdCl₂ (6) were characterized by single-crystal X-ray crystallography. The potentially tetradentate ligand enforces a tetrahedral geometry at each metal by adopting two coordination modes: κ²-NP (Al, Ga) and κ³-NP₂ (Cd).

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Dalton Transactions

Aluminium, zinc, gallium, and cadmium complexes supported by a monoanionic [N₂P₂] ligand

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