Issue 36, 2009
From the journal:

Dalton Transactions

A novel 3D Cd(ii) metal–organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline†

Xiuli Wang,*a   Guocheng Liu,a   Jinxia Zhang,a   Yongqiang Chen,a   Hongyan Lina  and  Wenyan Zhenga  

* Corresponding authors

a Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou, P. R. China
E-mail: wangxiuli@bhu.edu.cn
Fax: +86-416-3400158
Tel: +86-416-3400158

Abstract

A novel three dimensional cadmium metal–organic framework [Cd3(1,3-BDC)3(PIP)2]·8H2O (1) with an unprecedented (5,6)-connected topology has been synthesized from the hydrothermal reaction of cadmium(II) nitrate with the mixed ligands isophthalate acid (1,3-H2BDC) and 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline (PIP). Its fluorescence property and thermal stability were investigated.

Graphical abstract: A novel 3D Cd(ii) metal–organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline

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Article information

DOI
https://doi.org/10.1039/B907839H
Article type
Communication
Submitted
20 Apr 2009
Accepted
21 Jul 2009
First published
31 Jul 2009

Dalton Trans., 2009, 7347-7349

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A novel 3D Cd(II) metal–organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline

X. Wang, G. Liu, J. Zhang, Y. Chen, H. Lin and W. Zheng, Dalton Trans., 2009, 7347 DOI: 10.1039/B907839H

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