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Issue 2, 2009
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An enantiopure N,N,S scorpionate ligand derived from (+)-camphor

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Abstract

Reductive S–S bond cleavage of a disulfide precursor 3 obtained from a pyridine-catalyzed Peterson-type reaction starting from camphorpyrazole 1, thionyl chloride and 2-methyl-2-(methyldithio)propionaldehyde yields 2,2′-bis(camphorpyrazol-1-yl)-2-methylpropane-2-thiol (HSiprbpm3cam, 4); the first zinc complexes bearing this ligand exhibit κ3 coordination of the ligand.

Graphical abstract: An enantiopure N,N,S scorpionate ligand derived from (+)-camphor

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Publication details

The article was received on 03 Nov 2008, accepted on 07 Nov 2008 and first published on 25 Nov 2008


Article type: Communication
DOI: 10.1039/B819596J
Citation: Dalton Trans., 2009,0, 254-255
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    An enantiopure N,N,S scorpionate ligand derived from (+)-camphor

    T. Godau, F. Platzmann, F. W. Heinemann and N. Burzlaff, Dalton Trans., 2009, 0, 254
    DOI: 10.1039/B819596J

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