Heterocycles from cyclopropanes: applications in natural product synthesis

Cheryl A. Carson; Michael A. Kerr

doi:10.1039/B901245C

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Chemical Society Reviews

Issue 11, 2009

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Heterocycles from cyclopropanes: applications in natural product synthesis

Cheryl A. Carson and Michael A. Kerr

Chem. Soc. Rev., 2009, 38, 3051-3060

DOI: 10.1039/B901245C
Received 01 Apr 2009, First published on the web 10 Jul 2009
This article is part of the collection: Rapid complexity generation in natural product total synthesis

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Abstract
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The construction of heterocyclic compounds from activated cyclopropane derivatives offers an alternative strategy for the preparation of molecules that may be of interest from a structural or biological standpoint. Several newly developed methods provide access to densely functionalized heterocycles in a manner that can be considered useful for both diversity- and target-oriented synthetic approaches. This tutorial review focuses on the latter, describing recent developments and applications of cyclopropane ring-expansion reactions in natural product synthesis.

Abstract from Natural Product Updates 2010

A review, with 48 references, looking at the synthesis of heterocycles from cyclopropanes, and their application in the synthesis of natural products.

Abstract from Methods in Organic Synthesis 2010

A review, with 48 references, of the synthesis of heterocycles using cyclopropane ring-expansion reactions, and their application in the synthesis of natural products.

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