[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products

Elizabeth A. Ilardi; Craig E. Stivala; Armen Zakarian

doi:10.1039/B901177N

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Society Reviews > [3,3]-Sigmatropic rearr...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Society Reviews

Issue 11, 2009

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Tutorial Review

Previous Article | Next Article

[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products

Elizabeth A. Ilardi , Craig E. Stivala and Armen Zakarian

Chem. Soc. Rev., 2009, 38, 3133-3148

DOI: 10.1039/B901177N
Received 21 Apr 2009, First published on the web 02 Sep 2009
This article is part of the collection: Rapid complexity generation in natural product total synthesis

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

Among the fundamental chemical transformations in organic synthesis, the [3,3]-sigmatropic rearrangement occupies a unique position as a powerful, reliable, and well-defined method for the stereoselective construction of carbon–carbon or carbon–heteroatom bonds. While many other reactions can unite two subunits and create a new bond, the strengths of sigmatropic rearrangements derive from their ability to enable structural reorganization with unmatched build-up of complexity. Recent applications that illustrate [3,3]-sigmatropic processes as a key concept in the synthesis of complex natural products are described in this tutorial review, covering literature from about 2001 through early 2009.

Abstract from Natural Product Updates 2010

A review, with 33 references, looking at the applications of [3,3]-sigmatropic rearrangements to natural product synthesis.

This may take some time to load.

Terms & Conditions|Privacy |Accessibility|ACAP Enabled

Chemical Society Reviews

[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products

Log in (Free Access)

Log in (Subscriber Access)

Articles By