Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

Ramesh Giri; Bing-Feng Shi; Keary M. Engle; Nathan Maugel; Jin-Quan Yu

doi:10.1039/B816707A

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Chemical Society Reviews

Issue 11, 2009

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Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

Ramesh Giri , Bing-Feng Shi , Keary M. Engle , Nathan Maugel and Jin-Quan Yu

Chem. Soc. Rev., 2009, 38, 3242-3272

DOI: 10.1039/B816707A
Received 22 Jul 2009, First published on the web 01 Oct 2009
This article is part of the collection: Rapid complexity generation in natural product total synthesis

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Abstract
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This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon–hydrogen (C–H) bond activation through the lens of stereoselectivity. Research concerning both diastereoselectivity and enantioselectivity in C–H activation processes is examined, and the application of concepts in this area for the development of novel carbon–carbon and carbon–heteroatom bond-forming reactions is described. Throughout this review, an emphasis is placed on reactions that are (or may soon become) relevant in the realm of organic synthesis (221 references).

Abstract from Methods in Organic Synthesis 2010

A review, with 221 references, discussing metal-catalysed enantioselective and diastereoselective carbon–hydrogen bond activation, focussing on the functionalisation of unactivated C–H bonds through metal insertion.

Abstract from Catalysts & Catalysed Reactions 2010

A review, with 221 references, discussing metal-catalysed carbon–hydrogen bond activation resulting in stereoselective products.

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Ramesh Giri
Bing-Feng Shi
Keary M. Engle
Nathan Maugel
Jin-Quan Yu

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Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

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