Recent applications of intramolecular Diels–Alder reactions to natural product synthesis

Martin Juhl; David Tanner

doi:10.1039/B816703F

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Chemical Society Reviews

Issue 11, 2009

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Recent applications of intramolecular Diels–Alder reactions to natural product synthesis

Martin Juhl and David Tanner

Chem. Soc. Rev., 2009, 38, 2983-2992

DOI: 10.1039/B816703F
Received 26 Mar 2009, First published on the web 29 Jul 2009
This article is part of the collection: Rapid complexity generation in natural product total synthesis

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This tutorial review presents some recent examples of intramolecular Diels–Alder (IMDA) reactions as key complexity-generating steps in the total synthesis of structurally intricate natural products. The opportunities afforded by transannular (TADA) versions of the IMDA reaction in complex molecule assembly are also highlighted. The review is aimed at a wide audience, ranging from advanced undergraduates to seasoned practitioners of total synthesis; since this is an educational overview, only selected highlights from the period 2000–2009 are presented, along with chosen references to other, more comprehensive, reviews.

Abstract from Natural Product Updates 2010

A review, with 26 references, describing the applications of the Diels–Alder reaction in the synthesis of natural products.

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Recent applications of intramolecular Diels–Alder reactions to natural product synthesis

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