Phosphonate and sulfonate metal organic frameworks

George K. H. Shimizu; Ramanathan Vaidhyanathan; Jared M. Taylor

doi:10.1039/B802423P

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Chemical Society Reviews

Issue 5, 2009

The home of high impact reviews from across the chemical sciences.

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Critical Review

Phosphonate and sulfonate metal organic frameworks

George K. H. Shimizu,*^a Ramanathan Vaidhyanathan^a and Jared M. Taylor^a

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Department of Chemistry, University of Calgary, Calgary, Alberta, Canada
E-mail: gshimizu@ucalgary.ca ;
Fax: 1 403 289 9488 ;
Tel: 1 403 220 5347

Chem. Soc. Rev., 2009,38, 1430-1449

DOI: 10.1039/B802423P
Received 26 Jan 2009, First published online 12 Mar 2009

This article is part of themed collection: Metal Organic Frameworks

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Abstract
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Recent progress in phosphonate and sulfonate MOFs is reviewed with an emphasis on open frameworks. These two ligating functionalities are paired due to their structural analogy but the review will show that their differences likely outweigh their similarities when it comes to their framework structures and properties. Examples that are highlighted focus on new routes to open structures, demonstrations of porosity and functionality, and examples with dynamic structures. This critical review is geared to researchers interested in designing open framework solids (134 references).

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