Kinetic isotope effect for ground state proton transfer in the green fluorescent protein: a quantum-kinetic model

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Physical Chemistry Chemical Physics

Issue 38, 2009

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Hong Zhang , Sufan Wang , Qiao Sun and Sean C. Smith

Phys. Chem. Chem. Phys., 2009, 11, 8422-8424

DOI: 10.1039/B912507H
Received 24 Jun 2009, Accepted 23 Jul 2009
First published on the web 30 Jul 2009

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The calculated quantum mechanical kinetic isotope effects (KIE) agree nearly quantitatively with experimental KIE at room temperature.