2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

Tae Hwan Noh; Youn Jung Choi; Yoon Kyong Ryu; Young-A Lee; Ok-Sang Jung

doi:10.1039/B905296H

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CrystEngComm

Issue 11, 2009

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2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

Tae Hwan Noh , Youn Jung Choi , Yoon Kyong Ryu , Young-A Lee and Ok-Sang Jung

CrystEngComm, 2009, 11, 2371-2374

DOI: 10.1039/B905296H
Received 18 Mar 2009, Accepted 24 Jun 2009
First published on the web 23 Jul 2009

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Abstract
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The reaction of AgPF₆ in methanol with 1,3-dibromo-2,2-bis[(isonicotinoyloxy)methyl]propane (L) in dichloromethane affords an acentric diamondoid 3D silver(I) coordination polymer, [Ag(L)₂]_n(PF₆)_n with 2-fold interpenetration with alternating perpendicular “right-handed” and “left-handed” helical channel motifs induced by the bent ligand.

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Tae Hwan Noh
Youn Jung Choi
Yoon Kyong Ryu
Young-A Lee
Ok-Sang Jung

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CrystEngComm

2-Fold interpenetration via ligand-induced alternating perpendicular helical channel motifs. Structure of an acentric diamondoid silver(I) coordination polymer

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