A three-dimensional metal–organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies

Zhiyong Guo; Jiangbo Yu; Guanghua Li; Zhenjun Si; Huadong Guo; Hongjie Zhang

doi:10.1039/B903932E

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CrystEngComm

Issue 11, 2009

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A three-dimensional metal–organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies

Zhiyong Guo , Jiangbo Yu , Guanghua Li , Zhenjun Si , Huadong Guo and Hongjie Zhang

CrystEngComm, 2009, 11, 2254-2256

DOI: 10.1039/B903932E
Received 25 Feb 2009, Accepted 29 Jun 2009
First published on the web 24 Jul 2009

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Abstract
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A novel metal–organic framework [Cu₃(m-TATB)₂Py(CH₃OH)₂] (1) constructed of a triazine-based trigonal-planar ligand, 3,3′,3″-s-triazine-2,4,6-triyltribenzoate (m-H₃TATB), has been synthesized and structurally characterized. Compound 1 features three-dimensional (3D) channels and cavities together, and exhibits high carbon dioxide sorption at normal pressure.

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Ligand synthesis and characterisation, structural and PXRDdata, TGA and hydrogen sorption isotherms
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Zhiyong Guo
Jiangbo Yu
Guanghua Li
Zhenjun Si
Huadong Guo
Hongjie Zhang

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A three-dimensional metal–organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies

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