Single crystal cis–trans photoisomerizations of 2-(9-anthrylmethylene)-1-indanones

Jun Harada; Mayuko Harakawa; Shingo Sugiyama; Keiichiro Ogawa

doi:10.1039/B821900A

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CrystEngComm

Issue 7, 2009

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Single crystal cis–trans photoisomerizations of 2-(9-anthrylmethylene)-1-indanones

Jun Harada , Mayuko Harakawa , Shingo Sugiyama and Keiichiro Ogawa

CrystEngComm, 2009, 11, 1235-1239

DOI: 10.1039/B821900A
Received 08 Dec 2008, Accepted 16 Feb 2009
First published on the web 05 Mar 2009

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cis–trans Photoisomerizations of 2-(9-anthrylmethylene)-1-indanones were carried out in the solid state. The photoisomerizations proceeded without destruction of the crystal lattices. The crystal structural changes accompanying the photoisomerizations were observed by X-ray diffraction analysis. From the structural correlation between the reactants and products, the single-crystal isomerizations were proved to proceed through one bond flip (OBF), where the indanonyl moiety of the molecule rotates around the isomerizing double bond.

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Single crystal cis–trans photoisomerizations of 2-(9-anthrylmethylene)-1-indanones

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