An unprecedented all helical 3D network and a rarely observed non-interpenetrated octahedral network in homochiral Cu(II) MOFs: effect of steric bulk and π–π stacking interactions of the ligand backbone

Subhabrata Banerjee; N. N. Adarsh; Parthasarathi Dastidar

doi:10.1039/B820087B

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CrystEngComm

Issue 5, 2009

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An unprecedented all helical 3D network and a rarely observed non-interpenetrated octahedral network in homochiral Cu(II) MOFs: effect of steric bulk and π–π stacking interactions of the ligand backbone

Subhabrata Banerjee , N. N. Adarsh and Parthasarathi Dastidar

CrystEngComm, 2009, 11, 746-749

DOI: 10.1039/B820087B
Received 10 Nov 2008, Accepted 05 Jan 2009
First published on the web 03 Feb 2009

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Two bis-pyridyl-bis-amide based chiral ligands derived from L-phenylalanine and L-alanine resulted in an unprecedented all helical 3D network and a rarely observed microporous octahedral network in the corresponding homochiral Cu(II) MOFs. This remarkable structural difference displays the effect of amino acid side chain and ligating topology of the ligands on the supramolecular structures in these MOFs.

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An unprecedented all helical 3D network and a rarely observed non-interpenetrated octahedral network in homochiral Cu(II) MOFs: effect of steric bulk and π–π stacking interactions of the ligand backbone

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