Molecular tectonics: modulation of size and shape of cuboid 3-D coordination networks

Mei-Jin Lin; Abdelaziz Jouaiti; Nathalie Kyritsakas; Mir Wais Hosseini

doi:10.1039/B815695F

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CrystEngComm

Issue 1, 2009

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Molecular tectonics: modulation of size and shape of cuboid 3-D coordination networks

Mei-Jin Lin , Abdelaziz Jouaiti , Nathalie Kyritsakas and Mir Wais Hosseini

CrystEngComm, 2009, 11, 189-191

DOI: 10.1039/B815695F
Received 08 Sep 2008, Accepted 30 Sep 2008
First published on the web 03 Nov 2008

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Abstract
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The pore size and shape of cuboid 3-D coordination networks may be modulated by combining rigid neutral organic tectons of different length bearing two pyridines oriented in a divergent fashion with zinc dication and SiF₆ dianion behaving as a metallic node and as an inorganic tecton, respectively.

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Molecular tectonics: modulation of size and shape of cuboid 3-D coordination networks

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