Formation of pyrimidine dimer radical anions in the gas phase

Achim Edtbauer; Katherine Russell; Linda Feketeová; Jörg Taubitz; Christian Mitterdorfer; Stephan Denifl; Richard A. J. O’Hair; Tilmann D. Märk; Paul Scheier; Uta Wille

doi:10.1039/B920282J

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Chemical Communications

Issue 47, 2009

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Formation of pyrimidine dimer radical anions in the gas phase

Achim Edtbauer , Katherine Russell , Linda Feketeová , Jörg Taubitz , Christian Mitterdorfer , Stephan Denifl , Richard A. J. O’Hair , Tilmann D. Märk , Paul Scheier and Uta Wille

Chem. Commun., 2009, 7291-7293

DOI: 10.1039/B920282J
Received 29 Sep 2009, Accepted 20 Oct 2009
First published on the web 05 Nov 2009

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Crossed-beam experiments revealed that attachment of a free electron to the cyclobutane pyrimidine dimers c,s-DMT<>DMT and c,a-DMT<>DMT leads to the formation of dimer radical anions with the lifetime of at least 80 μs, thus showing that the latter are much more stable than previously believed.

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Chemical Communications

Formation of pyrimidine dimer radical anions in the gas phase

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