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Issue 47, 2009
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Formation of pyrimidine dimer radical anions in the gas phase

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Abstract

Crossed-beam experiments revealed that attachment of a free electron to the cyclobutane pyrimidine dimers c,s-DMT<>DMT and c,a-DMT<>DMT leads to the formation of dimer radical anions with the lifetime of at least 80 μs, thus showing that the latter are much more stable than previously believed.

Graphical abstract: Formation of pyrimidine dimer radical anions in the gas phase

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Publication details

The article was received on 29 Sep 2009, accepted on 20 Oct 2009 and first published on 05 Nov 2009


Article type: Communication
DOI: 10.1039/B920282J
Citation: Chem. Commun., 2009,0, 7291-7293
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    Formation of pyrimidine dimer radical anions in the gas phase

    A. Edtbauer, K. Russell, L. Feketeová, J. Taubitz, C. Mitterdorfer, S. Denifl, R. A. J. O’Hair, T. D. Märk, P. Scheier and U. Wille, Chem. Commun., 2009, 0, 7291
    DOI: 10.1039/B920282J

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