Controlling dimensionality in templated layer, chain and framework structures by combining metal fluorides with oxotetrahedra

Jessica Rouse; Kate V. Redrup; Eleni Kotsapa; Mark T. Weller

doi:10.1039/B917336F

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Chemical Communications

Issue 46, 2009

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Controlling dimensionality in templated layer, chain and framework structures by combining metal fluorides with oxotetrahedra

Jessica Rouse , Kate V. Redrup , Eleni Kotsapa and Mark T. Weller

Chem. Commun., 2009, 7209-7211

DOI: 10.1039/B917336F
Received 24 Aug 2009, Accepted 08 Oct 2009
First published on the web 19 Oct 2009

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The use of metal fluorides in hydrothermal reactions with linking phosphate and arsenate groups leads to the synthesis of numerous, frequently non-centrosymmetric, structures of controlled dimensionality.

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Detailed reaction conditions and unit cell parameters forcompounds 1?21
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Chemical Communications

Controlling dimensionality in templated layer, chain and framework structures by combining metal fluorides with oxotetrahedra

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