Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs

Ian R. Morgan; Angela Di Paolo; Dragoslav Vidovic; Ian A. Fallis; Simon Aldridge

doi:10.1039/B917304H

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Chemical Communications

Issue 47, 2009

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Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs

Ian R. Morgan , Angela Di Paolo , Dragoslav Vidovic , Ian A. Fallis and Simon Aldridge

Chem. Commun., 2009, 7288-7290

DOI: 10.1039/B917304H
Received 21 Aug 2009, Accepted 26 Oct 2009
First published on the web 04 Nov 2009

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Abstract
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A facile synthetic approach is reported for the synthesis of dissymmetric 1,2-ferrocenediyl Lewis acids and mixed acid–base pairs including the first example of a 1-phosphino-2-borylferrocene; the use of non-racemic electrophiles allows for the isolation of single diastereomer products.

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Preparative data for 2; crystallographic data for 2, 4 and 5
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Ian R. Morgan
Angela Di Paolo
Dragoslav Vidovic
Ian A. Fallis
Simon Aldridge

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Chemical Communications

Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs

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