A new MOF-505 analog exhibiting high acetylene storage

Yunxia Hu; Shengchang Xiang; Wenwei Zhang; Zhuxiu Zhang; Lei Wang; Junfeng Bai; Banglin Chen

doi:10.1039/B917046D

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Chemical Communications

Issue 48, 2009

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A new MOF-505 analog exhibiting high acetylene storage

Yunxia Hu , Shengchang Xiang , Wenwei Zhang , Zhuxiu Zhang , Lei Wang , Junfeng Bai and Banglin Chen

Chem. Commun., 2009, 7551-7553

DOI: 10.1039/B917046D
Received 18 Aug 2009, Accepted 22 Oct 2009
First published on the web 09 Nov 2009

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Abstract
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A new microporous metal–organic framework Cu₂(EBTC)(H₂O)₂·xG (EBTC = 1,1′-ethynebenzene-3,3′,5,5′-tetracarboxylate; G = guest molecule) was rationally designed with a NbO net, exhibiting significantly high acetylene storage of 252 and 160 cm³ g⁻¹ at 273 and 295 K under 1 bar, respectively.

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Experimental details, crystal, adsorption, desorption and TGAdata and hydrogen isotherm of 1a
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Yunxia Hu
Shengchang Xiang
Wenwei Zhang
Zhuxiu Zhang
Lei Wang
Junfeng Bai
Banglin Chen

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Chemical Communications

A new MOF-505 analog exhibiting high acetylene storage

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