Products of the iterative polyketide synthases in 9- and 10-membered enediyne biosynthesis

Huihua Sun; Rong Kong; Di Zhu; Min Lu; Qiang Ji; Chong Wai Liew; Julien Lescar; Guofu Zhong; Zhao-Xun Liang

doi:10.1039/B916751J

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Chemical Communications

Issue 47, 2009

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Products of the iterative polyketide synthases in 9- and 10-membered enediyne biosynthesis

Huihua Sun , Rong Kong , Di Zhu , Min Lu , Qiang Ji , Chong Wai Liew , Julien Lescar , Guofu Zhong and Zhao-Xun Liang

Chem. Commun., 2009, 7399-7401

DOI: 10.1039/B916751J
Received 14 Aug 2009, Accepted 13 Oct 2009
First published on the web 27 Oct 2009

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Abstract
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The iterative polyketide synthases from the biosynthetic pathways of three enediyne natural products were examined. The results established the all-trans conjugated pentadecaheptanene as the only major product shared by the PKSs. The experiments further revealed some intrinsic differences among the PKSs by demonstrating the formation of different by-products.

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Experimental procedures and enzymatic assay data
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Articles By

Huihua Sun
Rong Kong
Di Zhu
Min Lu
Qiang Ji
Chong Wai Liew
Julien Lescar
Guofu Zhong
Zhao-Xun Liang

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Chemical Communications

Products of the iterative polyketide synthases in 9- and 10-membered enediyne biosynthesis

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