Towards black chromophores: μ-oxo linked phthalocyanine–porphyrin dyads and phthalocyanine–subphthalocyanine dyad and triad arrays

Zhixin Zhao; Andrew N. Cammidge; Michael J. Cook

doi:10.1039/B916649A

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Chemical Communications

Issue 48, 2009

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Towards black chromophores: μ-oxo linked phthalocyanine–porphyrin dyads and phthalocyanine–subphthalocyanine dyad and triad arrays

Zhixin Zhao , Andrew N. Cammidge and Michael J. Cook

Chem. Commun., 2009, 7530-7532

DOI: 10.1039/B916649A
Received 13 Aug 2009, Accepted 22 Oct 2009
First published on the web 05 Nov 2009

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A versatile synthetic strategy based on the use of a non-peripherally substituted dihydroxysilicon phthalocyanine and dihydroxygermanium octaethylporphyrin has permitted controlled construction of heterodyads that absorb across the whole visible spectrum; the same phthalocyanine also reacts with chlorosubphthalocyanine to form a Si–O–B linked dyad and triad.

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Chemical Communications

Towards black chromophores: μ-oxo linked phthalocyanine–porphyrin dyads and phthalocyanine–subphthalocyanine dyad and triad arrays

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