Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

Josep Cornella; Carolina Sanchez; David Banawa; Igor Larrosa

doi:10.1039/B916646G

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Chemical Communications

Issue 46, 2009

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Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

Josep Cornella , Carolina Sanchez , David Banawa and Igor Larrosa

Chem. Commun., 2009, 7176-7178

DOI: 10.1039/B916646G
Received 13 Aug 2009, Accepted 22 Sep 2009
First published on the web 28 Oct 2009

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Abstract
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Catalytic amounts of Ag(I) salts in DMSO have been found to promote the protodecarboxylation of a wide variety of ortho-substituted benzoic acids under mild conditions and in excellent yields, highlighting a possible role for silver in decarboxylative cross-couplings.

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Chemical Communications

Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

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