A supramolecular hydrogel as a reusable heterogeneous catalyst for the direct aldol reaction

Francisco Rodríguez-Llansola; Juan F. Miravet; Beatriu Escuder

doi:10.1039/B916250J

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Chemical Communications

Issue 47, 2009

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A supramolecular hydrogel as a reusable heterogeneous catalyst for the direct aldol reaction

Francisco Rodríguez-Llansola , Juan F. Miravet and Beatriu Escuder

Chem. Commun., 2009, 7303-7305

DOI: 10.1039/B916250J
Received 06 Aug 2009, Accepted 26 Oct 2009
First published on the web 09 Nov 2009

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Abstract
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An L-proline based supramolecular hydrogel is used as an efficient heterogeneous organocatalyst for the direct aldol reaction with high stereoselectivity (up to 90% ee) and recyclability (up to 3 runs). The reversible nature of this self-assembled supramolecular system allows for easy recovery and regeneration of the catalyst.

Supplementary Info

Synthesis and characterization of compounds and additionaldetails of catalytic experiments
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Chemical Communications

A supramolecular hydrogel as a reusable heterogeneous catalyst for the direct aldol reaction

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