Enhanced electrochemiluminescence efficiency of Ru(II) derivative covalently linked carbon nanotubes hybrid

Jing Li; Li-Rong Guo; Wei Gao; Xing-Hua Xia; Li-Min Zheng

doi:10.1039/B916007H

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Chemical Communications

Issue 48, 2009

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Enhanced electrochemiluminescence efficiency of Ru(II) derivative covalently linked carbon nanotubes hybrid

Jing Li , Li-Rong Guo , Wei Gao , Xing-Hua Xia and Li-Min Zheng

Chem. Commun., 2009, 7545-7547

DOI: 10.1039/B916007H
Received 05 Aug 2009, Accepted 20 Oct 2009
First published on the web 06 Nov 2009

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Abstract
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The synthesized derivative Ru(bpy)₃ covalently linked CNTs hybrid shows good electrochemical activity and ca. 17 times higher luminescence quantum efficiency than the adsorbed derivative Ru(bpy)₃. The Ru-CNTs based ECL sensor exhibits high stability toward determination of TPA with a detection limit as low as 8.75 pM.

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Detailed experimental section, synthesis, absorption andfluorescence spectra, fluorescence image, IR, ESI-MS, andelectrodes preparation procedure
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Jing Li
Li-Rong Guo
Wei Gao
Xing-Hua Xia
Li-Min Zheng

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Chemical Communications

Enhanced electrochemiluminescence efficiency of Ru(II) derivative covalently linked carbon nanotubes hybrid

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