1,2-Olefin addition of a frustrated amine–borane Lewis pair

Jean-Baptiste Sortais; Tanja Voss; Gerald Kehr; Roland Fröhlich; Gerhard Erker

doi:10.1039/B915657G

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Chemical Communications

Issue 47, 2009

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1,2-Olefin addition of a frustrated amine–borane Lewis pair

Jean-Baptiste Sortais , Tanja Voss , Gerald Kehr , Roland Fröhlich and Gerhard Erker

Chem. Commun., 2009, 7417-7418

DOI: 10.1039/B915657G
Received 31 Jul 2009, Accepted 28 Sep 2009
First published on the web 26 Oct 2009

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Abstract
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Addition of B(C₆F₅)₃ to an α-dimethylamino-o-vinylferrocenophane system gives a frustrated Lewis pair that undergoes intramolecular 1,2-N–B addition to the alkene.

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Jean-Baptiste Sortais
Tanja Voss
Gerald Kehr
Roland Fröhlich
Gerhard Erker

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Chemical Communications

1,2-Olefin addition of a frustrated amine–borane Lewis pair

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