We demonstrate, by surface-assisted coupling of specifically designed molecular building blocks, the fabrication of regular two-dimensional polyphenylene networks with single-atom wide pores and sub-nanometer periodicity.
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Porous graphenes: two-dimensional polymer synthesis with atomic precision
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a
Empa, Swiss Federal Laboratories for Materials Testing and Research, nanotech@surfaces Laboratory, Feuerwerkerstrasse 39, 3602 Thun, Switzerland
E-mail: marco.bieri@empa.ch; roman.fasel@empa.ch ;
Fax: +41 44 823 40 34 ;
Tel: +41 44 823 43 48
E-mail: marco.bieri@empa.ch; roman.fasel@empa.ch ;
Fax: +41 44 823 40 34 ;
Tel: +41 44 823 43 48
b
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany
c
Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland
Chem. Commun., 2009, 6919-6921
DOI: 10.1039/B915190G
Received 27 Jul 2009, Accepted 03 Sep 2009
First published online 11 Sep 2009
Chemical Communications
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