Porous graphenes: two-dimensional polymer synthesis with atomic precision

Marco Bieri; Matthias Treier; Jinming Cai; Kamel Aït-Mansour; Pascal Ruffieux; Oliver Gröning; Pierangelo Gröning; Marcel Kastler; Ralph Rieger; Xinliang Feng; Klaus Müllen; Roman Fasel

doi:10.1039/B915190G

Porous graphenes: two-dimensional polymer synthesis with atomic precision†

Marco Bieri,*^a Matthias Treier,^a Jinming Cai,^a Kamel Aït-Mansour,^a Pascal Ruffieux,^a Oliver Gröning,^a Pierangelo Gröning,^a Marcel Kastler,‡^b Ralph Rieger,^b Xinliang Feng,^b Klaus Müllen^b and Roman Fasel*^ac

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* Corresponding authors

^a Empa, Swiss Federal Laboratories for Materials Testing and Research, nanotech@surfaces Laboratory, Feuerwerkerstrasse 39, 3602 Thun, Switzerland
E-mail: marco.bieri@empa.ch; roman.fasel@empa.ch
Fax: +41 44 823 40 34
Tel: +41 44 823 43 48

^b Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

^c Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland

Abstract

We demonstrate, by surface-assisted coupling of specifically designed molecular building blocks, the fabrication of regular two-dimensional polyphenylene networks with single-atom wide pores and sub-nanometer periodicity.

Chemical Communications

Porous graphenes: two-dimensional polymer synthesis with atomic precision†

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Porous graphenes: two-dimensional polymer synthesis with atomic precision

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