Splendid symmetry: crystallization of an unbridged isomer of Co2(CO)8 in Co2(CO)8·C60

Thelma Y. Garcia; James C. Fettinger; Marilyn M. Olmstead; Alan L. Balch

doi:10.1039/B915083H

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Chemical Communications

Issue 46, 2009

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Splendid symmetry: crystallization of an unbridged isomer of Co₂(CO)₈ in Co₂(CO)₈·C₆₀

Thelma Y. Garcia , James C. Fettinger , Marilyn M. Olmstead and Alan L. Balch

Chem. Commun., 2009, 7143-7145

DOI: 10.1039/B915083H
Received 24 Jul 2009, Accepted 09 Oct 2009
First published on the web 29 Oct 2009

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Abstract
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Cocrystallization of Co₂(CO)₈ with C₆₀ traps the cobalt carbonyl molecule as the D_3d isomer that otherwise is not available for crystallographic analysis.

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Chemical Communications

Splendid symmetry: crystallization of an unbridged isomer of Co₂(CO)₈ in Co₂(CO)₈·C₆₀

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