Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)3][SbF6] (M = Au, Ag, Cu)

Mauro Fianchini; Huixiong Dai; H. V. Rasika Dias

doi:10.1039/B915076E

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Chemical Communications

Issue 42, 2009

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Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)₃][SbF₆] (M = Au, Ag, Cu)

Mauro Fianchini , Huixiong Dai and H. V. Rasika Dias

Chem. Commun., 2009, 6373-6375

DOI: 10.1039/B915076E
Received 24 Jul 2009, Accepted 16 Sep 2009
First published on the web 28 Sep 2009

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Abstract
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Three closely related organometallic “spoke–wheel” complexes featuring coinage metal ions, Au(I), Ag(I), and Cu(I), bonded to three norbornene molecules in trigonal planar fashion have been isolated and completely characterized using several methods including X-ray crystallography.

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Synthesis and experimental details and X-ray crystallographicdata for [M(norbornene)₃][SbF₆]
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Crystal structure data
TXT (36K)

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Chemical Communications

Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)₃][SbF₆] (M = Au, Ag, Cu)

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